Interestingly, this EVAP - CANISTER PURGE SWITCH / purge vacuum diagnostic switch / purge sensor 12555984 shows up in the internet-based GM parts usage catalogs as being used with LT1s in F and Y cars, but not B and D. Unintentional omission perhaps? It is listed in the General Information: Part Numbers section of the SS Handbook PDF.
Relevant DTCs if it's malfunctioning, missing, or detecting a problem:
P0441 - EVAP System No Flow During Purge
P0443 - EVAP Purge Solenoid Control Circuit
P1441 - EVAP System Flow During Non-Purge
Although the FSM doesn't explicitly state so, I wouldn't be surprised if those faults also limited or restricted the solenoid purge valve (which is controlled by the PCM) from opening, or from attempting to operate "normally" while driving. This is pure conjecture, based on how I have seen more modern EVAP systems function. Not enough purge = oversaturated canister, leading to breakthrough (vapors can then escape out the fresh air inlet) but in practice there's always going to be some "breakthrough" on any vehicle with cracks or leaks in the vapor hose leading back to the fuel tank.